Atomization Characteristics of Hydrogen Peroxide Solutions in Electrostatic Field

Hydrogen peroxide (H(2)O(2)) can be considered as a sterilant or a green propellant. For a common use in industrial application, spray is an effective method to form fine H(2)O(2) droplets. In this paper, electrostatic atomization based on the configuration of needle ring electrodes is proposed to produce H(2)O(2) spray by minimizing its effective surface tension. The breakup performances of H(2)O(2) ligaments can be improved by increasing the electric field intensity, reducing the nozzle size, and adjusting suitable volume flow rate. The smallest average diameter of breakup droplets for 35 wt. % concentration H(2)O(2) solution reached 92.8 μm under optimum operation conditions. The H(2)O(2) concentration significantly influenced the breakup performance owing to the concentration effect on comprehensive physical properties such as density, surface tension, viscosity, and permittivity. The average diameters of breakup droplets decreased with decreasing H(2)O(2) concentration. At 8 wt. % concentration, the average breakup droplet diameter was reduced to 67.4 μm. Finally, electrostatic atomization mechanism of H(2)O(2) solution was analyzed by calculating dimensionless parameters of Re, We, and Oh numbers with the combination of the operation conditions and physical properties for in-depth understanding the breakup behaviors. The calculation showed that the minimum average diameter of breakup droplets was obtained at 8 wt. % concentration at the investigated range of H(2)O(2) concentration, which kept in agreement with the experimental results.