Removal of MS2 and fr Bacteriophages Using MgAl(2)O(4)-Modified, Al(2)O(3)-Stabilized Porous Ceramic Granules for Drinking Water Treatment

Point-of-use ceramic filters are one of the strategies to address problems associated with waterborne diseases to remove harmful microorganisms in water sources prior to its consumption. In this study, development of adsorption-based ceramic depth filters composed of alumina platelets was achieved using spray granulation (calcined at 800 °C). Their virus retention performance was assessed using cartridges containing granular material (4 g) with two virus surrogates: MS2 and fr bacteriophages. Both materials showed complete removal, with a 7 log(10) reduction value (LRV) of MS2 up to 1 L. MgAl(2)O(4)-modified Al(2)O(3) granules possessed a higher MS2 retention capacity, contrary to the shortcomings of retention limits in pure Al(2)O(3) granules. No significant decline in the retention of fr occurred during filtration tests up to 2 L. The phase composition and morphology of the materials were preserved during filtration, with no magnesium or aluminum leakage during filtration, as confirmed by X-ray diffractograms, electron micrographs, and inductively coupled plasma-optical emission spectrometry. The proposed MgAl(2)O(4)-modified Al(2)O(3) granular ceramic filter materials offer high virus retention, achieving the criterion for virus filtration as required by the World Health Organization (LRV ≥ 4). Owing to their high thermal and chemical stability, the developed materials are thus suitable for thermal and chemical-free regeneration treatments.