Cargando…
Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water
Different groups of organic micropollutants including pharmaceuticals and pesticides have emerged in the environment in the last years, resulting in a rise in environmental and human health risks. In order to face up and evaluate these risks, there is an increasing need to assess their occurrence in...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9146997/ https://www.ncbi.nlm.nih.gov/pubmed/35630644 http://dx.doi.org/10.3390/molecules27103167 |
_version_ | 1784716699681947648 |
---|---|
author | Tadić, Đorđe Manasfi, Rayana Bertrand, Marine Sauvêtre, Andrés Chiron, Serge |
author_facet | Tadić, Đorđe Manasfi, Rayana Bertrand, Marine Sauvêtre, Andrés Chiron, Serge |
author_sort | Tadić, Đorđe |
collection | PubMed |
description | Different groups of organic micropollutants including pharmaceuticals and pesticides have emerged in the environment in the last years, resulting in a rise in environmental and human health risks. In order to face up and evaluate these risks, there is an increasing need to assess their occurrence in the environment. Therefore, many studies in the past couple of decades were focused on the improvements in organic micropollutants’ extraction efficiency from the different environmental matrices, as well as their mass spectrometry detection parameters and acquisition modes. This paper presents different sampling methodologies and high-resolution mass spectrometry-based non-target screening workflows for the identification of pharmaceuticals, pesticides, and their transformation products in different kinds of water (domestic wastewater and river water). Identification confidence was increased including retention time prediction in the workflow. The applied methodology, using a passive sampling technique, allowed for the identification of 85 and 47 contaminants in the wastewater effluent and river water, respectively. Finally, contaminants’ prioritization was performed through semi-quantification in grab samples as a fundamental step for monitoring schemes. |
format | Online Article Text |
id | pubmed-9146997 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-91469972022-05-29 Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water Tadić, Đorđe Manasfi, Rayana Bertrand, Marine Sauvêtre, Andrés Chiron, Serge Molecules Article Different groups of organic micropollutants including pharmaceuticals and pesticides have emerged in the environment in the last years, resulting in a rise in environmental and human health risks. In order to face up and evaluate these risks, there is an increasing need to assess their occurrence in the environment. Therefore, many studies in the past couple of decades were focused on the improvements in organic micropollutants’ extraction efficiency from the different environmental matrices, as well as their mass spectrometry detection parameters and acquisition modes. This paper presents different sampling methodologies and high-resolution mass spectrometry-based non-target screening workflows for the identification of pharmaceuticals, pesticides, and their transformation products in different kinds of water (domestic wastewater and river water). Identification confidence was increased including retention time prediction in the workflow. The applied methodology, using a passive sampling technique, allowed for the identification of 85 and 47 contaminants in the wastewater effluent and river water, respectively. Finally, contaminants’ prioritization was performed through semi-quantification in grab samples as a fundamental step for monitoring schemes. MDPI 2022-05-16 /pmc/articles/PMC9146997/ /pubmed/35630644 http://dx.doi.org/10.3390/molecules27103167 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Tadić, Đorđe Manasfi, Rayana Bertrand, Marine Sauvêtre, Andrés Chiron, Serge Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title | Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title_full | Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title_fullStr | Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title_full_unstemmed | Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title_short | Use of Passive and Grab Sampling and High-Resolution Mass Spectrometry for Non-Targeted Analysis of Emerging Contaminants and Their Semi-Quantification in Water |
title_sort | use of passive and grab sampling and high-resolution mass spectrometry for non-targeted analysis of emerging contaminants and their semi-quantification in water |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9146997/ https://www.ncbi.nlm.nih.gov/pubmed/35630644 http://dx.doi.org/10.3390/molecules27103167 |
work_keys_str_mv | AT tadicđorđe useofpassiveandgrabsamplingandhighresolutionmassspectrometryfornontargetedanalysisofemergingcontaminantsandtheirsemiquantificationinwater AT manasfirayana useofpassiveandgrabsamplingandhighresolutionmassspectrometryfornontargetedanalysisofemergingcontaminantsandtheirsemiquantificationinwater AT bertrandmarine useofpassiveandgrabsamplingandhighresolutionmassspectrometryfornontargetedanalysisofemergingcontaminantsandtheirsemiquantificationinwater AT sauvetreandres useofpassiveandgrabsamplingandhighresolutionmassspectrometryfornontargetedanalysisofemergingcontaminantsandtheirsemiquantificationinwater AT chironserge useofpassiveandgrabsamplingandhighresolutionmassspectrometryfornontargetedanalysisofemergingcontaminantsandtheirsemiquantificationinwater |