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Effect of Spatial Inhomogeneity on Quantum Trapping

[Image: see text] An object that is immersed in a fluid and approaching a substrate may find a potential energy minimum at a certain distance due to the balance between attractive and repulsive Casimir–Lifshitz forces, a phenomenon referred to as quantum trapping. This equilibrium depends on the rel...

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Autores principales: Esteso, Victoria, Carretero-Palacios, Sol, Míguez, Hernán
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9150094/
https://www.ncbi.nlm.nih.gov/pubmed/35576163
http://dx.doi.org/10.1021/acs.jpclett.2c00807
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author Esteso, Victoria
Carretero-Palacios, Sol
Míguez, Hernán
author_facet Esteso, Victoria
Carretero-Palacios, Sol
Míguez, Hernán
author_sort Esteso, Victoria
collection PubMed
description [Image: see text] An object that is immersed in a fluid and approaching a substrate may find a potential energy minimum at a certain distance due to the balance between attractive and repulsive Casimir–Lifshitz forces, a phenomenon referred to as quantum trapping. This equilibrium depends on the relative values of the dielectric functions of the materials involved. Herein, we study quantum trapping effects in planar nanocomposite materials and demonstrate that they are strongly dependent on the characteristics of the spatial inhomogeneity. As a model case, we consider spherical particles embedded in an otherwise homogeneous material. We propose an effective medium approximation that accounts for the effect of inclusions and find that an unprecedented and counterintuitive intense repulsive Casimir–Lifshitz force arises as a result of the strong optical scattering and absorption size-dependent resonances caused by their presence. Our results imply that the proper analysis of quantum trapping effects requires comprehensive knowledge and a detailed description of the potential inhomogeneity (caused by imperfections, pores, inclusions, and density variations) present in the materials involved.
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spelling pubmed-91500942022-05-31 Effect of Spatial Inhomogeneity on Quantum Trapping Esteso, Victoria Carretero-Palacios, Sol Míguez, Hernán J Phys Chem Lett [Image: see text] An object that is immersed in a fluid and approaching a substrate may find a potential energy minimum at a certain distance due to the balance between attractive and repulsive Casimir–Lifshitz forces, a phenomenon referred to as quantum trapping. This equilibrium depends on the relative values of the dielectric functions of the materials involved. Herein, we study quantum trapping effects in planar nanocomposite materials and demonstrate that they are strongly dependent on the characteristics of the spatial inhomogeneity. As a model case, we consider spherical particles embedded in an otherwise homogeneous material. We propose an effective medium approximation that accounts for the effect of inclusions and find that an unprecedented and counterintuitive intense repulsive Casimir–Lifshitz force arises as a result of the strong optical scattering and absorption size-dependent resonances caused by their presence. Our results imply that the proper analysis of quantum trapping effects requires comprehensive knowledge and a detailed description of the potential inhomogeneity (caused by imperfections, pores, inclusions, and density variations) present in the materials involved. American Chemical Society 2022-05-16 2022-05-26 /pmc/articles/PMC9150094/ /pubmed/35576163 http://dx.doi.org/10.1021/acs.jpclett.2c00807 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Esteso, Victoria
Carretero-Palacios, Sol
Míguez, Hernán
Effect of Spatial Inhomogeneity on Quantum Trapping
title Effect of Spatial Inhomogeneity on Quantum Trapping
title_full Effect of Spatial Inhomogeneity on Quantum Trapping
title_fullStr Effect of Spatial Inhomogeneity on Quantum Trapping
title_full_unstemmed Effect of Spatial Inhomogeneity on Quantum Trapping
title_short Effect of Spatial Inhomogeneity on Quantum Trapping
title_sort effect of spatial inhomogeneity on quantum trapping
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9150094/
https://www.ncbi.nlm.nih.gov/pubmed/35576163
http://dx.doi.org/10.1021/acs.jpclett.2c00807
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