Preparation of a ε-caprolactonic diterpenoid derivate by unexpected oxidative cleavage/lactonization of 2-oxoaustroeupatol

From aerial parts of Austroeupatorium inulifolium was isolated the ent-nor-furano triol labdane austroeupatol 1. The compound 1 was treated with IBX showing an unexpected selectivity at the potentially oxidizable sites of the substrate yielding the 2-oxoaustroeupatol (2) and 2,19-dioxoaustroeupatol...

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Detalles Bibliográficos
Autores principales: Chacón-Morales, Pablo A., Amaro-Luis, Juan M., Rojas Fermín, Luis Beltrán, Jacquet, Rémi, Deffieux, Denis, Pouységu, Laurent, Quideau, Stéphane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Nature Singapore 2022
Materias:
Short Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9156645/
https://www.ncbi.nlm.nih.gov/pubmed/35641706
http://dx.doi.org/10.1007/s13659-022-00343-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9156645/
https://www.ncbi.nlm.nih.gov/pubmed/35641706
http://dx.doi.org/10.1007/s13659-022-00343-2

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