Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups

An efficient one-pot procedure has been developed for the synthesis of previously unknown 1,1′-(9-selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium dibromides containing acetal moieties via transan­nular addition of selenium dibromide to Z,Z-cycloocta-1,5-diene, followed by reaction with pyridine-3-...

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Detalles Bibliográficos
Autores principales: Musalov, M. V., Zhivet’eva, S. A., Shkurchenko, I. V., Amosova, S. V., Potapov, V. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Pleiades Publishing 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9156833/
http://dx.doi.org/10.1134/S1070428022040236
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author Musalov, M. V.
Zhivet’eva, S. A.
Shkurchenko, I. V.
Amosova, S. V.
Potapov, V. A.
author_facet Musalov, M. V.
Zhivet’eva, S. A.
Shkurchenko, I. V.
Amosova, S. V.
Potapov, V. A.
author_sort Musalov, M. V.
collection PubMed
description An efficient one-pot procedure has been developed for the synthesis of previously unknown 1,1′-(9-selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium dibromides containing acetal moieties via transan­nular addition of selenium dibromide to Z,Z-cycloocta-1,5-diene, followed by reaction with pyridine-3- and 4-carbaldehyde acetals. The yields of the target products range from 80 to 97%.
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spelling pubmed-91568332022-06-02 Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups Musalov, M. V. Zhivet’eva, S. A. Shkurchenko, I. V. Amosova, S. V. Potapov, V. A. Russ J Org Chem Article An efficient one-pot procedure has been developed for the synthesis of previously unknown 1,1′-(9-selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium dibromides containing acetal moieties via transan­nular addition of selenium dibromide to Z,Z-cycloocta-1,5-diene, followed by reaction with pyridine-3- and 4-carbaldehyde acetals. The yields of the target products range from 80 to 97%. Pleiades Publishing 2022-06-01 2022 /pmc/articles/PMC9156833/ http://dx.doi.org/10.1134/S1070428022040236 Text en © Pleiades Publishing, Ltd. 2022 This article is made available via the PMC Open Access Subset for unrestricted research re-use and secondary analysis in any form or by any means with acknowledgement of the original source. These permissions are granted for the duration of the World Health Organization (WHO) declaration of COVID-19 as a global pandemic.
spellingShingle Article
Musalov, M. V.
Zhivet’eva, S. A.
Shkurchenko, I. V.
Amosova, S. V.
Potapov, V. A.
Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title_full Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title_fullStr Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title_full_unstemmed Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title_short Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
title_sort synthesis of 2,6-dibromo-9-selenabicyclo[3.3.1]nonane-based pyridinium salts containing acetal groups
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9156833/
http://dx.doi.org/10.1134/S1070428022040236
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