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Isolation of the Elusive Heptavanadate Anion with Trisalkoxide Ligands
[Image: see text] The unprecedented heptavanadate cluster has been isolated from reactions between trisalkoxide ligands and vanadate in water at pH = 2 as a series of alkylammonium [H(x)V(7)O(18)(H(2)O)((OCH(2))(3)CR)]((4–x)-) salts (1–3, R = CH(2)OH; 4, R = CH(3)). Their structures have been determ...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9157487/ https://www.ncbi.nlm.nih.gov/pubmed/33818060 http://dx.doi.org/10.1021/acs.inorgchem.1c00448 |
Sumario: | [Image: see text] The unprecedented heptavanadate cluster has been isolated from reactions between trisalkoxide ligands and vanadate in water at pH = 2 as a series of alkylammonium [H(x)V(7)O(18)(H(2)O)((OCH(2))(3)CR)]((4–x)-) salts (1–3, R = CH(2)OH; 4, R = CH(3)). Their structures have been determined and the partial stability of 4 in water assessed by a combination of multinuclear NMR spectroscopy and ESI-MS. The heptavanadate unit reported herein could represent an intermediate species in the formation of decavanadate that is blocked by attachment of tripodal ligands. |
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