Cargando…
Regioselective synthesis of spirocyclic pyrrolines via a palladium-catalyzed Narasaka–Heck/C–H activation/[4 + 2] annulation cascade reaction
A novel palladium-catalyzed spirocyclization through sequential Narasaka–Heck cyclization, C–H activation and [4 + 2] annulation has been developed. In this reaction, cheap and readily available 2-chlorobenzoic acid or ethyl phenylpropiolate was employed as the C2 insertion unit to react with γ,δ-un...
Autores principales: | Wei, Wan-Xu, Kong, Xiangtao, Jiao, Rui-Qiang, Li, Xue-Song, Wang, Cui-Tian, Li, Yuke, Liang, Yong-Min |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159093/ https://www.ncbi.nlm.nih.gov/pubmed/35733897 http://dx.doi.org/10.1039/d2sc01887j |
Ejemplares similares
-
What the Heck?—Automated
Regioselectivity Calculations
of Palladium-Catalyzed Heck Reactions Using Quantum Chemistry
por: Ree, Nicolai, et al.
Publicado: (2022) -
Enantioselective Narasaka–Heck cyclizations: synthesis of tetrasubstituted nitrogen-bearing stereocenters
por: Race, Nicholas J., et al.
Publicado: (2017) -
Rapid Access to Spirocyclized Indolenines via Palladium-Catalyzed
Cascade Reactions of Tryptamine Derivatives and Propargyl Carbonate
por: Montgomery, Thomas D., et al.
Publicado: (2014) -
A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes
por: Fu, Wai Chung, et al.
Publicado: (2019) -
Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides
por: Fan, Tao, et al.
Publicado: (2017)