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Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution

The selenium-π-acid-catalysis has received increasing attention as a powerful tool for olefin functionalization, but the regioselectivity is often problematic. Reported herein is a selenium-catalyzed regiocontrolled olefin transpositional chlorination and imidation reaction. The reaction outcome ben...

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Detalles Bibliográficos
Autores principales: Yang, Ling, Liu, Yuan, Fan, Wen-Xin, Tan, Dong-Hang, Li, Qingjiang, Wang, Honggen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159098/
https://www.ncbi.nlm.nih.gov/pubmed/35733886
http://dx.doi.org/10.1039/d2sc00954d