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A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol

A novel environmental nano-catalyst based on zeolite (ZE) adjusted with carbon nanotube/silver nanoparticles (Ag/CNT) ornamented carbon paste electrode (CPE) is used for electrochemical oxidation of propylene glycol (PG) in 0.5 M H(2)SO(4) solution. The techniques like cyclic voltammetry (CV), chron...

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Autores principales: Abdel-Gawad, Soha A., Fekry, Amany M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9160039/
https://www.ncbi.nlm.nih.gov/pubmed/35650287
http://dx.doi.org/10.1038/s41598-022-12268-4
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author Abdel-Gawad, Soha A.
Fekry, Amany M.
author_facet Abdel-Gawad, Soha A.
Fekry, Amany M.
author_sort Abdel-Gawad, Soha A.
collection PubMed
description A novel environmental nano-catalyst based on zeolite (ZE) adjusted with carbon nanotube/silver nanoparticles (Ag/CNT) ornamented carbon paste electrode (CPE) is used for electrochemical oxidation of propylene glycol (PG) in 0.5 M H(2)SO(4) solution. The techniques like cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are utilized to achieve the catalytic activity performance. Surface characteristics are achieved by means of scanning electron microscope (SEM) and Energy dispersive X-ray analysis (EDX) techniques. Enhancing the loading magnitude of CNT into catalyst's ingredient can meaningfully develop the catalytic activity of the electrocatalyst towards propylene oxidation. The impact of altering the concentration of propylene glycol and the scanning rate on the resulting electrocatalyst performance during the oxidation cycle is considered. Chronoamperograms present an amplify of the steady state oxidation current density values after addition of these nano-catalysts. A promising catalytic stability of nano-catalyst has been achieved in electing its use for propylene glycol electro-oxidation in fuel cells applications.
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spelling pubmed-91600392022-06-03 A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol Abdel-Gawad, Soha A. Fekry, Amany M. Sci Rep Article A novel environmental nano-catalyst based on zeolite (ZE) adjusted with carbon nanotube/silver nanoparticles (Ag/CNT) ornamented carbon paste electrode (CPE) is used for electrochemical oxidation of propylene glycol (PG) in 0.5 M H(2)SO(4) solution. The techniques like cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are utilized to achieve the catalytic activity performance. Surface characteristics are achieved by means of scanning electron microscope (SEM) and Energy dispersive X-ray analysis (EDX) techniques. Enhancing the loading magnitude of CNT into catalyst's ingredient can meaningfully develop the catalytic activity of the electrocatalyst towards propylene oxidation. The impact of altering the concentration of propylene glycol and the scanning rate on the resulting electrocatalyst performance during the oxidation cycle is considered. Chronoamperograms present an amplify of the steady state oxidation current density values after addition of these nano-catalysts. A promising catalytic stability of nano-catalyst has been achieved in electing its use for propylene glycol electro-oxidation in fuel cells applications. Nature Publishing Group UK 2022-06-01 /pmc/articles/PMC9160039/ /pubmed/35650287 http://dx.doi.org/10.1038/s41598-022-12268-4 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Abdel-Gawad, Soha A.
Fekry, Amany M.
A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title_full A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title_fullStr A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title_full_unstemmed A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title_short A novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
title_sort novel environmental nano-catalyst of zeolite amended with carbon nanotube/silver nanoparticles decorated carbon paste electrode for electro-oxidation of propylene glycol
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9160039/
https://www.ncbi.nlm.nih.gov/pubmed/35650287
http://dx.doi.org/10.1038/s41598-022-12268-4
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