Cargando…

Archimedean Spirals Form at Low Flow Rates in Confined Chemical Gardens

[Image: see text] We describe and study the formation of confined chemical garden patterns. At low flow rates of injection of cobalt chloride solution into a Hele-Shaw cell filled with sodium silicate, the precipitate forms with a thin filament wrapping around an expanding “candy floss” structure. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Rocha, Luis A. M., Thorne, Lewis, Wong, Jasper J., Cartwright, Julyan H. E., Cardoso, Silvana S. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9161446/
https://www.ncbi.nlm.nih.gov/pubmed/35593590
http://dx.doi.org/10.1021/acs.langmuir.2c00633
Descripción
Sumario:[Image: see text] We describe and study the formation of confined chemical garden patterns. At low flow rates of injection of cobalt chloride solution into a Hele-Shaw cell filled with sodium silicate, the precipitate forms with a thin filament wrapping around an expanding “candy floss” structure. The result is the formation of an Archimedean spiral structure. We model the growth of the structure mathematically. We estimate the effective density of the precipitate and calculate the membrane permeability. We set the results within the context of recent experimental and modeling work on confined chemical garden filaments.