Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis

[Image: see text] The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction h...

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Autores principales: Guerrero-Corella, Andrea, Fraile, Alberto, Alemán, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9164241/
https://www.ncbi.nlm.nih.gov/pubmed/35673681
http://dx.doi.org/10.1021/acsorginorgau.1c00053
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author Guerrero-Corella, Andrea
Fraile, Alberto
Alemán, José
author_facet Guerrero-Corella, Andrea
Fraile, Alberto
Alemán, José
author_sort Guerrero-Corella, Andrea
collection PubMed
description [Image: see text] The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes.
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spelling pubmed-91642412022-06-05 Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis Guerrero-Corella, Andrea Fraile, Alberto Alemán, José ACS Org Inorg Au [Image: see text] The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes. American Chemical Society 2022-02-03 /pmc/articles/PMC9164241/ /pubmed/35673681 http://dx.doi.org/10.1021/acsorginorgau.1c00053 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Guerrero-Corella, Andrea
Fraile, Alberto
Alemán, José
Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title_full Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title_fullStr Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title_full_unstemmed Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title_short Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
title_sort intramolecular hydrogen-bond activation: strategies, benefits, and influence in catalysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9164241/
https://www.ncbi.nlm.nih.gov/pubmed/35673681
http://dx.doi.org/10.1021/acsorginorgau.1c00053
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