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Total syntheses of ent-hypocoprin A and ent-hypocoprin B
This study reports the stereoselective total syntheses of the antipodes of the unique 3/10 bicyclic skeletal sesquiterpenoids, namely, hypocoprin A and hypocoprin B. The synthesis involved conjugate addition accelerated by trimethylsilyl chloride, construction of the ten-membered ring via the intram...
Autores principales: | Ota, Koichiro, Watanabe, Taiki, Igarashi, Shuntaro, Okazaki, Shinnosuke, Kamaike, Kazuo, Miyaoka, Hiroaki |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9169068/ https://www.ncbi.nlm.nih.gov/pubmed/35754888 http://dx.doi.org/10.1039/d2ra02891c |
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