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Proton-coupled electron transfer of macrocyclic ring hydrogenation: The chlorinphlorin

Redox noninnocence of pyrrole macrocycles allows for their hydrogenation by proton-coupled electron transfer (PCET). The initial reduction of porphyrins by PCET occurs at a bridging methine carbon, yielding a phlorin. In macrocyclic cores that are reduced beyond porphyrins, the phlorin is unusual. T...

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Detalles Bibliográficos
Autores principales:	Sun, Rui, Liu, Mengran, Zheng, Shao-Liang, Dogutan, Dilek K., Costentin, Cyrille, Nocera, Daniel G.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	National Academy of Sciences 2022
Materias:	Physical Sciences
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9171799/ https://www.ncbi.nlm.nih.gov/pubmed/35533271 http://dx.doi.org/10.1073/pnas.2122063119

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