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Directed, nickel-catalyzed 1,2-alkylsulfenylation of alkenyl carbonyl compounds

We report a regioselective, nickel-catalyzed syn-1,2-carbosulfenylation of non-conjugated alkenyl carbonyl compounds with alkyl/arylzinc nucleophiles and tailored N–S electrophiles. This method allows the simultaneous installation of a variety of C(sp(3)) and S(Ar) (or Se(Ar)) groups onto unactivate...

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Detalles Bibliográficos
Autores principales: Li, Zi-Qi, He, Wen-Ji, Ni, Hui-Qi, Engle, Keary M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9172569/
https://www.ncbi.nlm.nih.gov/pubmed/35756518
http://dx.doi.org/10.1039/d2sc01563c

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