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Interplay between the Directing Group and Multifunctional Acetate Ligand in Pd-Catalyzed anti-Acetoxylation of Unsymmetrical Dialkyl-Substituted Alkynes

[Image: see text] The cooperative action of the acetate ligand, the 2-pyridyl sulfonyl (SO(2)Py) directing group on the alkyne substrate, and the palladium catalyst has been shown to be crucial for controlling reactivity, regioselectivity, and stereoselectivity in the acetoxylation of unsymmetrical...

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Detalles Bibliográficos
Autores principales:	Corpas, Javier, Arpa, Enrique M., Lapierre, Romain, Corral, Inés, Mauleón, Pablo, Arrayás, Ramón Gómez, Carretero, Juan C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9173690/ https://www.ncbi.nlm.nih.gov/pubmed/35692253 http://dx.doi.org/10.1021/acscatal.2c00710

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