Unexpected Imidazole Coordination to the Dirhodium Center in a Protein Environment: Insights from X-ray Crystallography and Quantum Chemistry

[Image: see text] X-ray diffraction data demonstrate that the adduct formed upon the reaction of dirhodium(II,II) tetraacetate with RNase A reacts with imidazole, leading to the formation of an unexpected product with the imidazole that binds the dirhodium center at an equatorial site rather than an...

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Detalles Bibliográficos
Autores principales: Loreto, Domenico, Fasulo, Francesca, Muñoz-García, Ana B., Pavone, Michele, Merlino, Antonello
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9175176/
https://www.ncbi.nlm.nih.gov/pubmed/35609175
http://dx.doi.org/10.1021/acs.inorgchem.2c01370

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