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One-electron bonds in copper–aluminum and copper–gallium complexes

Odd-electron bonds have unique electronic structures and are often encountered as transiently stable, homonuclear species. In this study, a pair of copper complexes supported by Group 13 metalloligands, M[N((o-C(6)H(4))NCH(2)P(i)Pr(2))(3)] (M = Al or Ga), featuring two-center/one-electron (2c/1e) σ-...

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Detalles Bibliográficos
Autores principales: Graziano, Brendan J., Scott, Thais R., Vollmer, Matthew V., Dorantes, Michael J., Young, Victor G., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9176199/
https://www.ncbi.nlm.nih.gov/pubmed/35756529
http://dx.doi.org/10.1039/d2sc01998a