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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation
A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KO(t)Bu as an additive, the reaction time and activation...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Bentham Science Publishers
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9178507/ https://www.ncbi.nlm.nih.gov/pubmed/33319688 http://dx.doi.org/10.2174/1570179417666201214112514 |
| Sumario: | A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KO(t)Bu as an additive, the reaction time and activation energy are greatly reduced. |
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