The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen

The role of ligands in the regulation of the catalytic activity of Ni-complexes (Ni(acac)(2)) in green process-selective ethylbenzene oxidation with O(2) into α-phenyl ethyl hydroperoxide is considered in this article. The dual function of phenol (PhOH) included in the coordination sphere of the nic...

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Autores principales: Ludmila, Matienko, Irina, Zhigacheva, Elena, Mil, Anastasia, Albantova, Alexander, Goloshchapov
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182165/
https://www.ncbi.nlm.nih.gov/pubmed/35684440
http://dx.doi.org/10.3390/molecules27113502
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author Ludmila, Matienko
Irina, Zhigacheva
Elena, Mil
Anastasia, Albantova
Alexander, Goloshchapov
author_facet Ludmila, Matienko
Irina, Zhigacheva
Elena, Mil
Anastasia, Albantova
Alexander, Goloshchapov
author_sort Ludmila, Matienko
collection PubMed
description The role of ligands in the regulation of the catalytic activity of Ni-complexes (Ni(acac)(2)) in green process-selective ethylbenzene oxidation with O(2) into α-phenyl ethyl hydroperoxide is considered in this article. The dual function of phenol (PhOH) included in the coordination sphere of the nickel complex as an antioxidant or catalyst depends on the ligand environment of the metal. The role of intermolecular H-bonds and supramolecular structures (AFM method) in the mechanisms of selective catalysis by nickel complexes in chemical and biological oxidation reactions is analyzed.
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spelling pubmed-91821652022-06-10 The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen Ludmila, Matienko Irina, Zhigacheva Elena, Mil Anastasia, Albantova Alexander, Goloshchapov Molecules Article The role of ligands in the regulation of the catalytic activity of Ni-complexes (Ni(acac)(2)) in green process-selective ethylbenzene oxidation with O(2) into α-phenyl ethyl hydroperoxide is considered in this article. The dual function of phenol (PhOH) included in the coordination sphere of the nickel complex as an antioxidant or catalyst depends on the ligand environment of the metal. The role of intermolecular H-bonds and supramolecular structures (AFM method) in the mechanisms of selective catalysis by nickel complexes in chemical and biological oxidation reactions is analyzed. MDPI 2022-05-30 /pmc/articles/PMC9182165/ /pubmed/35684440 http://dx.doi.org/10.3390/molecules27113502 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ludmila, Matienko
Irina, Zhigacheva
Elena, Mil
Anastasia, Albantova
Alexander, Goloshchapov
The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title_full The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title_fullStr The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title_full_unstemmed The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title_short The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen
title_sort dual function of phoh included in the coordination sphere of the nickel complexes in the processes of oxidation with dioxygen
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182165/
https://www.ncbi.nlm.nih.gov/pubmed/35684440
http://dx.doi.org/10.3390/molecules27113502
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