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Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in soluti...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182544/ https://www.ncbi.nlm.nih.gov/pubmed/35684306 http://dx.doi.org/10.3390/molecules27113368 |
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author | Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf |
author_facet | Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf |
author_sort | Roesler, Fabian |
collection | PubMed |
description | A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state. |
format | Online Article Text |
id | pubmed-9182544 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-91825442022-06-10 Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf Molecules Article A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state. MDPI 2022-05-24 /pmc/articles/PMC9182544/ /pubmed/35684306 http://dx.doi.org/10.3390/molecules27113368 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title | Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title_full | Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title_fullStr | Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title_full_unstemmed | Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title_short | Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes |
title_sort | asymmetrically substituted phospholes as ligands for coinage metal complexes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182544/ https://www.ncbi.nlm.nih.gov/pubmed/35684306 http://dx.doi.org/10.3390/molecules27113368 |
work_keys_str_mv | AT roeslerfabian asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes AT bruhnclemens asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes AT pietschnigrudolf asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes |