Cargando…

Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes

A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in soluti...

Descripción completa

Detalles Bibliográficos
Autores principales: Roesler, Fabian, Bruhn, Clemens, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182544/
https://www.ncbi.nlm.nih.gov/pubmed/35684306
http://dx.doi.org/10.3390/molecules27113368
_version_ 1784724060981166080
author Roesler, Fabian
Bruhn, Clemens
Pietschnig, Rudolf
author_facet Roesler, Fabian
Bruhn, Clemens
Pietschnig, Rudolf
author_sort Roesler, Fabian
collection PubMed
description A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state.
format Online
Article
Text
id pubmed-9182544
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-91825442022-06-10 Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes Roesler, Fabian Bruhn, Clemens Pietschnig, Rudolf Molecules Article A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state. MDPI 2022-05-24 /pmc/articles/PMC9182544/ /pubmed/35684306 http://dx.doi.org/10.3390/molecules27113368 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Roesler, Fabian
Bruhn, Clemens
Pietschnig, Rudolf
Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title_full Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title_fullStr Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title_full_unstemmed Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title_short Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes
title_sort asymmetrically substituted phospholes as ligands for coinage metal complexes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9182544/
https://www.ncbi.nlm.nih.gov/pubmed/35684306
http://dx.doi.org/10.3390/molecules27113368
work_keys_str_mv AT roeslerfabian asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes
AT bruhnclemens asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes
AT pietschnigrudolf asymmetricallysubstitutedphospholesasligandsforcoinagemetalcomplexes