Cargando…
Arsolyl-supported intermetallic dative bonding
The first examples of late transition metal η(5)-arsolyls [Image: see text] (L = CO, P(OMe)(3); R = Ph, Me, Et, SiMe(3); R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = Pt(II), Au(I), Hg(II)) through both conventional As → M and polar-covalent (dative) Co → M interac...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200119/ https://www.ncbi.nlm.nih.gov/pubmed/35774176 http://dx.doi.org/10.1039/d2sc01200f |
| _version_ | 1784727994286211072 |
|---|---|
| author | Kirk, Ryan M. Hill, Anthony F. |
| author_facet | Kirk, Ryan M. Hill, Anthony F. |
| author_sort | Kirk, Ryan M. |
| collection | PubMed |
| description | The first examples of late transition metal η(5)-arsolyls [Image: see text] (L = CO, P(OMe)(3); R = Ph, Me, Et, SiMe(3); R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = Pt(II), Au(I), Hg(II)) through both conventional As → M and polar-covalent (dative) Co → M interactions. |
| format | Online Article Text |
| id | pubmed-9200119 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-92001192022-06-29 Arsolyl-supported intermetallic dative bonding Kirk, Ryan M. Hill, Anthony F. Chem Sci Chemistry The first examples of late transition metal η(5)-arsolyls [Image: see text] (L = CO, P(OMe)(3); R = Ph, Me, Et, SiMe(3); R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = Pt(II), Au(I), Hg(II)) through both conventional As → M and polar-covalent (dative) Co → M interactions. The Royal Society of Chemistry 2022-05-04 /pmc/articles/PMC9200119/ /pubmed/35774176 http://dx.doi.org/10.1039/d2sc01200f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
| spellingShingle | Chemistry Kirk, Ryan M. Hill, Anthony F. Arsolyl-supported intermetallic dative bonding |
| title | Arsolyl-supported intermetallic dative bonding |
| title_full | Arsolyl-supported intermetallic dative bonding |
| title_fullStr | Arsolyl-supported intermetallic dative bonding |
| title_full_unstemmed | Arsolyl-supported intermetallic dative bonding |
| title_short | Arsolyl-supported intermetallic dative bonding |
| title_sort | arsolyl-supported intermetallic dative bonding |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200119/ https://www.ncbi.nlm.nih.gov/pubmed/35774176 http://dx.doi.org/10.1039/d2sc01200f |
| work_keys_str_mv | AT kirkryanm arsolylsupportedintermetallicdativebonding AT hillanthonyf arsolylsupportedintermetallicdativebonding |