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Arsolyl-supported intermetallic dative bonding
The first examples of late transition metal η(5)-arsolyls [Image: see text] (L = CO, P(OMe)(3); R = Ph, Me, Et, SiMe(3); R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = Pt(II), Au(I), Hg(II)) through both conventional As → M and polar-covalent (dative) Co → M interac...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200119/ https://www.ncbi.nlm.nih.gov/pubmed/35774176 http://dx.doi.org/10.1039/d2sc01200f |