Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene

[Image: see text] We report a facile synthesis of MXene/bismuth ferrite (Ti(3)C(2)T(x) @ BiFeO(3)) nanocomposites using hydrazine hydrate induced with the hydrothermal method. Preparation of the composite with hydrazine hydrate prevents the formation of Bi(25)FeO(39) inside the matrix. The 25 wt % l...

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Autores principales: Koneru, Bhargavi, Swapnalin, Jhilmil, Natarajan, Srinivasan, Franco Jr, Adolfo, Banerjee, Prasun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9201885/
https://www.ncbi.nlm.nih.gov/pubmed/35721946
http://dx.doi.org/10.1021/acsomega.2c02471
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author Koneru, Bhargavi
Swapnalin, Jhilmil
Natarajan, Srinivasan
Franco Jr, Adolfo
Banerjee, Prasun
author_facet Koneru, Bhargavi
Swapnalin, Jhilmil
Natarajan, Srinivasan
Franco Jr, Adolfo
Banerjee, Prasun
author_sort Koneru, Bhargavi
collection PubMed
description [Image: see text] We report a facile synthesis of MXene/bismuth ferrite (Ti(3)C(2)T(x) @ BiFeO(3)) nanocomposites using hydrazine hydrate induced with the hydrothermal method. Preparation of the composite with hydrazine hydrate prevents the formation of Bi(25)FeO(39) inside the matrix. The 25 wt % loading of BiFeO(3) acts as spacers for the multilayer restacking of MXene flakes by retaining the (002) plane. This promotes large dc conductivity with interfacial and defect dipole polarization mechanisms inside the composite material. The thinner M-H loop also indicates the minimal magnetic loss inside the composites. The facile synthesis strategy provides outstanding properties in Ti(3)C(2)T(x) @ BiFeO(3) composites as two-dimensional multiferroic materials.
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spelling pubmed-92018852022-06-17 Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene Koneru, Bhargavi Swapnalin, Jhilmil Natarajan, Srinivasan Franco Jr, Adolfo Banerjee, Prasun ACS Omega [Image: see text] We report a facile synthesis of MXene/bismuth ferrite (Ti(3)C(2)T(x) @ BiFeO(3)) nanocomposites using hydrazine hydrate induced with the hydrothermal method. Preparation of the composite with hydrazine hydrate prevents the formation of Bi(25)FeO(39) inside the matrix. The 25 wt % loading of BiFeO(3) acts as spacers for the multilayer restacking of MXene flakes by retaining the (002) plane. This promotes large dc conductivity with interfacial and defect dipole polarization mechanisms inside the composite material. The thinner M-H loop also indicates the minimal magnetic loss inside the composites. The facile synthesis strategy provides outstanding properties in Ti(3)C(2)T(x) @ BiFeO(3) composites as two-dimensional multiferroic materials. American Chemical Society 2022-06-03 /pmc/articles/PMC9201885/ /pubmed/35721946 http://dx.doi.org/10.1021/acsomega.2c02471 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Koneru, Bhargavi
Swapnalin, Jhilmil
Natarajan, Srinivasan
Franco Jr, Adolfo
Banerjee, Prasun
Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title_full Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title_fullStr Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title_full_unstemmed Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title_short Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene
title_sort intercalation of nanoscale multiferroic spacers between the two-dimensional interlayers of mxene
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9201885/
https://www.ncbi.nlm.nih.gov/pubmed/35721946
http://dx.doi.org/10.1021/acsomega.2c02471
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