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Oxidative Addition of Water to Ir(I) Complexes Bearing a Pincer-Type Silyl Ligand
[Image: see text] Reaction of water with in situ generated [(PSiP-R)Ir(I)] (PSiP-R = [{2-(R(2)P)C(6)H(4)}(2)MeSi](−); R = cyclohexyl, tBu or iPr) from [(PSiP-R)Ir(H)(4)] and tert-butylethylene (tbe) showed high ligand dependency. Oxidative addition of water cleanly proceeded in the reaction of [(PSi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9201899/ https://www.ncbi.nlm.nih.gov/pubmed/35721963 http://dx.doi.org/10.1021/acsomega.2c02168 |