Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)

[Image: see text] Elemental chalcogens react with [Fe(CN)(2)(CO)(3)](2–) to give the following ferrous derivatives: [K(18-crown-6)](2)[Fe(S(5))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(S(2))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Se(4))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Te(2))(CN)(2)(CO)(2)], and (N...

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Autores principales: Zhang, Yu, Woods, Toby, Rauchfuss, Thomas B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9202235/
https://www.ncbi.nlm.nih.gov/pubmed/35561009
http://dx.doi.org/10.1021/acs.inorgchem.2c00684
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author Zhang, Yu
Woods, Toby
Rauchfuss, Thomas B.
author_facet Zhang, Yu
Woods, Toby
Rauchfuss, Thomas B.
author_sort Zhang, Yu
collection PubMed
description [Image: see text] Elemental chalcogens react with [Fe(CN)(2)(CO)(3)](2–) to give the following ferrous derivatives: [K(18-crown-6)](2)[Fe(S(5))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(S(2))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Se(4))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Te(2))(CN)(2)(CO)(2)], and (NEt(4))(2)[Fe(Te(2))(CN)(2)(CO)(2)]. While these complex anions crystallized in a single stereochemistry (i.e., trans dicyanides or cis dicyanides), they isomerize in solution upon irradiation. The results are benchmarked by the corresponding studies on benzyl thiolate [K(18-crown-6)](2)[Fe(SBn)(2)(CN)(2)(CO)(2)].
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spelling pubmed-92022352023-05-13 Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te) Zhang, Yu Woods, Toby Rauchfuss, Thomas B. Inorg Chem [Image: see text] Elemental chalcogens react with [Fe(CN)(2)(CO)(3)](2–) to give the following ferrous derivatives: [K(18-crown-6)](2)[Fe(S(5))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(S(2))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Se(4))(CN)(2)(CO)(2)], [K(18-crown-6)](2)[Fe(Te(2))(CN)(2)(CO)(2)], and (NEt(4))(2)[Fe(Te(2))(CN)(2)(CO)(2)]. While these complex anions crystallized in a single stereochemistry (i.e., trans dicyanides or cis dicyanides), they isomerize in solution upon irradiation. The results are benchmarked by the corresponding studies on benzyl thiolate [K(18-crown-6)](2)[Fe(SBn)(2)(CN)(2)(CO)(2)]. American Chemical Society 2022-05-13 2022-05-30 /pmc/articles/PMC9202235/ /pubmed/35561009 http://dx.doi.org/10.1021/acs.inorgchem.2c00684 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Zhang, Yu
Woods, Toby
Rauchfuss, Thomas B.
Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title_full Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title_fullStr Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title_full_unstemmed Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title_short Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E(x))(CN)(2)(CO)(2)](2–) (E = S, Se, or Te)
title_sort synthesis and dynamics of ferrous polychalcogenides [fe(e(x))(cn)(2)(co)(2)](2–) (e = s, se, or te)
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9202235/
https://www.ncbi.nlm.nih.gov/pubmed/35561009
http://dx.doi.org/10.1021/acs.inorgchem.2c00684
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