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Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions

[Image: see text] 3,3′-Methylenedisalicylic acid (MDS) was synthesized and ascertained on the basis of elemental analyses (C, H) and spectral measurements (IR, mass, (1)H NMR, and UV–vis). Moreover, the prepared MDS compound has been assayed for its antimicrobial action against the growth of fungi a...

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Autores principales: Ahmed, Ayman H., Sherif, El-Sayed M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9202282/
https://www.ncbi.nlm.nih.gov/pubmed/35721908
http://dx.doi.org/10.1021/acsomega.2c00194
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author Ahmed, Ayman H.
Sherif, El-Sayed M.
author_facet Ahmed, Ayman H.
Sherif, El-Sayed M.
author_sort Ahmed, Ayman H.
collection PubMed
description [Image: see text] 3,3′-Methylenedisalicylic acid (MDS) was synthesized and ascertained on the basis of elemental analyses (C, H) and spectral measurements (IR, mass, (1)H NMR, and UV–vis). Moreover, the prepared MDS compound has been assayed for its antimicrobial action against the growth of fungi as well as Gram-positive and Gram-negative bacteria. The results demonstrated the possibility of its usefulness to restrain the growth of both fungi and bacteria, whereas MDS showed its best impact against Candida albicans. The inhibitive impact of MDS on the corrosion of aluminum (Al) in concentrated sodium chloride solution (3.5 wt % NaCl) has been investigated. The corrosion work was done by potentiodynamic cyclic polarization, electrochemical impedance spectroscopy, and chronoamperometric current–time measurements and complemented by scanning electron microscopy and energy-dispersive X-ray investigations. It was found that MDS molecules protect the aluminum against corrosion, and its ability increases with the increase of concentration from 5 × 10(–5) to 1 × 10(–4) M and further to 5 × 10(–4) M. The electrochemical results were supported by the morphological analysis and proved that the presence of MDS inhibits the uniform and pitting corrosion of Al in the chloride solutions.
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spelling pubmed-92022822022-06-17 Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions Ahmed, Ayman H. Sherif, El-Sayed M. ACS Omega [Image: see text] 3,3′-Methylenedisalicylic acid (MDS) was synthesized and ascertained on the basis of elemental analyses (C, H) and spectral measurements (IR, mass, (1)H NMR, and UV–vis). Moreover, the prepared MDS compound has been assayed for its antimicrobial action against the growth of fungi as well as Gram-positive and Gram-negative bacteria. The results demonstrated the possibility of its usefulness to restrain the growth of both fungi and bacteria, whereas MDS showed its best impact against Candida albicans. The inhibitive impact of MDS on the corrosion of aluminum (Al) in concentrated sodium chloride solution (3.5 wt % NaCl) has been investigated. The corrosion work was done by potentiodynamic cyclic polarization, electrochemical impedance spectroscopy, and chronoamperometric current–time measurements and complemented by scanning electron microscopy and energy-dispersive X-ray investigations. It was found that MDS molecules protect the aluminum against corrosion, and its ability increases with the increase of concentration from 5 × 10(–5) to 1 × 10(–4) M and further to 5 × 10(–4) M. The electrochemical results were supported by the morphological analysis and proved that the presence of MDS inhibits the uniform and pitting corrosion of Al in the chloride solutions. American Chemical Society 2022-06-01 /pmc/articles/PMC9202282/ /pubmed/35721908 http://dx.doi.org/10.1021/acsomega.2c00194 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ahmed, Ayman H.
Sherif, El-Sayed M.
Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title_full Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title_fullStr Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title_full_unstemmed Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title_short Methylenedisalicylic Acid as a Biocorrosion Inhibitor for Aluminum in Concentrated Sodium Chloride Solutions
title_sort methylenedisalicylic acid as a biocorrosion inhibitor for aluminum in concentrated sodium chloride solutions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9202282/
https://www.ncbi.nlm.nih.gov/pubmed/35721908
http://dx.doi.org/10.1021/acsomega.2c00194
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