Synthesis of MeOH and DME From CO(2) Hydrogenation Over Commercial and Modified Catalysts

Growing concern about climate change has been driving the search for solutions to mitigate greenhouse gas emissions. In this context, carbon capture and utilization (CCU) technologies have been proposed and developed as a way of giving CO(2) a sustainable and economically viable destination. An interesting approach is the conversion of CO(2) into valuable chemicals, such as methanol (MeOH) and dimethyl ether (DME), by means of catalytic hydrogenation on Cu-, Zn-, and Al-based catalysts. In this work, three catalysts were tested for the synthesis of MeOH and DME from CO(2) using a single fixed-bed reactor. The first one was a commercial CuO/γ-Al(2)O(3); the second one was CuO-ZnO/γ-Al(2)O(3), obtained via incipient wetness impregnation of the first catalyst with an aqueous solution of zinc acetate; and the third one was a CZA catalyst obtained by the coprecipitation method. The samples were characterized by XRD, XRF, and N(2) adsorption isotherms. The hydrogenation of CO(2) was performed at 25 bar, 230°C, with a H(2):CO(2) ratio of 3 and space velocity of 1,200 ml (g cat · h)(−1) in order to assess the potential of these catalysts in the conversion of CO(2) to methanol and dimethyl ether. The catalyst activity was correlated to the adsorption isotherms of each reactant. The main results show that the highest CO(2) conversion and the best yield of methanol are obtained with the CZACP catalyst, very likely due to its higher adsorption capacity of H(2). In addition, although the presence of zinc oxide reduces the textural properties of the porous catalyst, CZAWI showed higher CO(2) conversion than commercial catalyst CuO/γ-Al(2)O(3).