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Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures

In the present investigation, an attempt has been made to evaluate internal pressure [Formula: see text] , energy [Formula: see text] , and enthalpy of vaporization [Formula: see text] along with excess entropy [Formula: see text] and excess isothermal compressibility [Formula: see text] for binary...

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Autores principales: Prabhune, Aditi, Natekar, Amrita, Dey, Ranjan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204321/
https://www.ncbi.nlm.nih.gov/pubmed/35720983
http://dx.doi.org/10.3389/fchem.2022.868836
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author Prabhune, Aditi
Natekar, Amrita
Dey, Ranjan
author_facet Prabhune, Aditi
Natekar, Amrita
Dey, Ranjan
author_sort Prabhune, Aditi
collection PubMed
description In the present investigation, an attempt has been made to evaluate internal pressure [Formula: see text] , energy [Formula: see text] , and enthalpy of vaporization [Formula: see text] along with excess entropy [Formula: see text] and excess isothermal compressibility [Formula: see text] for binary solutions of alkanones (2-propanone, 2-butanone, and 2-heptanone) and aromatic amines (aniline, N-methylaniline, and pyridine) at 293.15, 298.15, and 303.15 K, respectively. The cohesive energy density (CED) and solubility parameter [Formula: see text] are studied to understand the strength of molecular interactions. The coefficient of thermal expansion [Formula: see text] and isothermal compressibility [Formula: see text] have also been investigated using empirical equations and have been employed to understand the molecular interactions. All the evaluated properties have been used to understand the nature and extent of intermolecular interactions taking place. The observed trends in the properties and their variations have been discussed in terms of varying chain lengths of the alkyl group and the hydrogen bonding capability of the components. The findings show that the extent of interactions follows an order: aniline > NMA > pyridine, keeping the alkanone constant at all the temperatures under study.
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spelling pubmed-92043212022-06-18 Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures Prabhune, Aditi Natekar, Amrita Dey, Ranjan Front Chem Chemistry In the present investigation, an attempt has been made to evaluate internal pressure [Formula: see text] , energy [Formula: see text] , and enthalpy of vaporization [Formula: see text] along with excess entropy [Formula: see text] and excess isothermal compressibility [Formula: see text] for binary solutions of alkanones (2-propanone, 2-butanone, and 2-heptanone) and aromatic amines (aniline, N-methylaniline, and pyridine) at 293.15, 298.15, and 303.15 K, respectively. The cohesive energy density (CED) and solubility parameter [Formula: see text] are studied to understand the strength of molecular interactions. The coefficient of thermal expansion [Formula: see text] and isothermal compressibility [Formula: see text] have also been investigated using empirical equations and have been employed to understand the molecular interactions. All the evaluated properties have been used to understand the nature and extent of intermolecular interactions taking place. The observed trends in the properties and their variations have been discussed in terms of varying chain lengths of the alkyl group and the hydrogen bonding capability of the components. The findings show that the extent of interactions follows an order: aniline > NMA > pyridine, keeping the alkanone constant at all the temperatures under study. Frontiers Media S.A. 2022-05-26 /pmc/articles/PMC9204321/ /pubmed/35720983 http://dx.doi.org/10.3389/fchem.2022.868836 Text en Copyright © 2022 Prabhune, Natekar and Dey. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Prabhune, Aditi
Natekar, Amrita
Dey, Ranjan
Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title_full Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title_fullStr Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title_full_unstemmed Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title_short Thermophysical Properties of Alkanone + Aromatic Amine Mixtures at Varying Temperatures
title_sort thermophysical properties of alkanone + aromatic amine mixtures at varying temperatures
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9204321/
https://www.ncbi.nlm.nih.gov/pubmed/35720983
http://dx.doi.org/10.3389/fchem.2022.868836
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