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Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent

Pesticides are among the most dangerous developing toxins since they are very hazardous to the environment and threaten human health. In this study, researchers successfully manufactured surface-modified magnetic diatomite (m-DE-APTES) and used them as a sorbent to extract endosulfan from an aqueous...

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Autor principal: Alacabey, İhsan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9205645/
https://www.ncbi.nlm.nih.gov/pubmed/35720987
http://dx.doi.org/10.3389/fchem.2022.907302
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author Alacabey, İhsan
author_facet Alacabey, İhsan
author_sort Alacabey, İhsan
collection PubMed
description Pesticides are among the most dangerous developing toxins since they are very hazardous to the environment and threaten human health. In this study, researchers successfully manufactured surface-modified magnetic diatomite (m-DE-APTES) and used them as a sorbent to extract endosulfan from an aqueous solution. There is no other study like it in the scholarly literature, and the results are astounding. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), electron spin resonance (ESR), and surface area measurements were used to analyze magnetic diatomite particles with surface modification. According to the analysis results, magnetic diatomite has a wide surface area and a porous structure. Furthermore, m-DE-APTES has a higher endosulfan adsorption capacity (97.2 mg g(−1)) than raw diatomite (DE) (16.6 mg g(−1)). Adsorption statistics agree with Langmuir adsorption isotherm (R (2) = 0.9905), and the adsorption occurred spontaneously at −2.576 kj mol(−1) in terms of ΔG(o). Finally, m-DE-APTES are a viable alternative adsorbent for removing pesticides from aqueous solutions.
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spelling pubmed-92056452022-06-18 Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent Alacabey, İhsan Front Chem Chemistry Pesticides are among the most dangerous developing toxins since they are very hazardous to the environment and threaten human health. In this study, researchers successfully manufactured surface-modified magnetic diatomite (m-DE-APTES) and used them as a sorbent to extract endosulfan from an aqueous solution. There is no other study like it in the scholarly literature, and the results are astounding. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), electron spin resonance (ESR), and surface area measurements were used to analyze magnetic diatomite particles with surface modification. According to the analysis results, magnetic diatomite has a wide surface area and a porous structure. Furthermore, m-DE-APTES has a higher endosulfan adsorption capacity (97.2 mg g(−1)) than raw diatomite (DE) (16.6 mg g(−1)). Adsorption statistics agree with Langmuir adsorption isotherm (R (2) = 0.9905), and the adsorption occurred spontaneously at −2.576 kj mol(−1) in terms of ΔG(o). Finally, m-DE-APTES are a viable alternative adsorbent for removing pesticides from aqueous solutions. Frontiers Media S.A. 2022-05-26 /pmc/articles/PMC9205645/ /pubmed/35720987 http://dx.doi.org/10.3389/fchem.2022.907302 Text en Copyright © 2022 Alacabey. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Alacabey, İhsan
Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title_full Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title_fullStr Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title_full_unstemmed Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title_short Endosulfan Elimination Using Amine-Modified Magnetic Diatomite as an Adsorbent
title_sort endosulfan elimination using amine-modified magnetic diatomite as an adsorbent
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9205645/
https://www.ncbi.nlm.nih.gov/pubmed/35720987
http://dx.doi.org/10.3389/fchem.2022.907302
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