I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters

A novel, I(2)-mediated tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters has been developed under mild conditions. Different kinds of 4H-benzo[d][1,3]thiazin-2-ylphosphonate could be synthesized in moderate to excellent yields. This method has the advantages of easy...

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Detalles Bibliográficos
Autores principales: Liu, Yang, Wu, Wenjin, Sang, Xiaoyan, Xia, Yu, Fang, Guojian, Hao, Wenyan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9207709/
https://www.ncbi.nlm.nih.gov/pubmed/35800309
http://dx.doi.org/10.1039/d2ra03072a
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author Liu, Yang
Wu, Wenjin
Sang, Xiaoyan
Xia, Yu
Fang, Guojian
Hao, Wenyan
author_facet Liu, Yang
Wu, Wenjin
Sang, Xiaoyan
Xia, Yu
Fang, Guojian
Hao, Wenyan
author_sort Liu, Yang
collection PubMed
description A novel, I(2)-mediated tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters has been developed under mild conditions. Different kinds of 4H-benzo[d][1,3]thiazin-2-ylphosphonate could be synthesized in moderate to excellent yields. This method has the advantages of easy access to raw materials, free-metal catalyst, simple operation, high yield and high functional group tolerance.
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spelling pubmed-92077092022-07-06 I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters Liu, Yang Wu, Wenjin Sang, Xiaoyan Xia, Yu Fang, Guojian Hao, Wenyan RSC Adv Chemistry A novel, I(2)-mediated tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters has been developed under mild conditions. Different kinds of 4H-benzo[d][1,3]thiazin-2-ylphosphonate could be synthesized in moderate to excellent yields. This method has the advantages of easy access to raw materials, free-metal catalyst, simple operation, high yield and high functional group tolerance. The Royal Society of Chemistry 2022-06-20 /pmc/articles/PMC9207709/ /pubmed/35800309 http://dx.doi.org/10.1039/d2ra03072a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liu, Yang
Wu, Wenjin
Sang, Xiaoyan
Xia, Yu
Fang, Guojian
Hao, Wenyan
I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title_full I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title_fullStr I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title_full_unstemmed I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title_short I(2)-mediated Csp(2)–P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
title_sort i(2)-mediated csp(2)–p bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9207709/
https://www.ncbi.nlm.nih.gov/pubmed/35800309
http://dx.doi.org/10.1039/d2ra03072a
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