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Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst

In this study, metal–organic framework based on molybdenum and piperidine-4-carboxylic acid, was synthesized through a simple solvothermal method and employed as an effective catalyst for biodiesel production from oleic acid and palmitic acid via esterification reaction. The prepared catalyst was ch...

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Autores principales: Ghorbani-Choghamarani, Arash, Taherinia, Zahra, Tyula, Yunes Abbasi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9209509/
https://www.ncbi.nlm.nih.gov/pubmed/35725895
http://dx.doi.org/10.1038/s41598-022-14341-4
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author Ghorbani-Choghamarani, Arash
Taherinia, Zahra
Tyula, Yunes Abbasi
author_facet Ghorbani-Choghamarani, Arash
Taherinia, Zahra
Tyula, Yunes Abbasi
author_sort Ghorbani-Choghamarani, Arash
collection PubMed
description In this study, metal–organic framework based on molybdenum and piperidine-4-carboxylic acid, was synthesized through a simple solvothermal method and employed as an effective catalyst for biodiesel production from oleic acid and palmitic acid via esterification reaction. The prepared catalyst was characterized by XRD, FTIR, TGA, DSC, BET, SEM, TEM, ICP-OES, X-ray mapping and EDX analysis. The resulting Mo–MOF catalyst exhibit a rod-like morphology, specific surface area of 56 m(2)/g, and thermal stability up to 300 °C. The solid catalyst exhibited high activities for esterification of oleic acid and palmitic acid. Moreover, the catalyst could be simply recovered and efficiently reutilized for several times without significant loss in its activity, also obtained results revealed that metal–organic framework could be used for the appropriate and rapid biodiesel production.
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spelling pubmed-92095092022-06-22 Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst Ghorbani-Choghamarani, Arash Taherinia, Zahra Tyula, Yunes Abbasi Sci Rep Article In this study, metal–organic framework based on molybdenum and piperidine-4-carboxylic acid, was synthesized through a simple solvothermal method and employed as an effective catalyst for biodiesel production from oleic acid and palmitic acid via esterification reaction. The prepared catalyst was characterized by XRD, FTIR, TGA, DSC, BET, SEM, TEM, ICP-OES, X-ray mapping and EDX analysis. The resulting Mo–MOF catalyst exhibit a rod-like morphology, specific surface area of 56 m(2)/g, and thermal stability up to 300 °C. The solid catalyst exhibited high activities for esterification of oleic acid and palmitic acid. Moreover, the catalyst could be simply recovered and efficiently reutilized for several times without significant loss in its activity, also obtained results revealed that metal–organic framework could be used for the appropriate and rapid biodiesel production. Nature Publishing Group UK 2022-06-20 /pmc/articles/PMC9209509/ /pubmed/35725895 http://dx.doi.org/10.1038/s41598-022-14341-4 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Ghorbani-Choghamarani, Arash
Taherinia, Zahra
Tyula, Yunes Abbasi
Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title_full Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title_fullStr Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title_full_unstemmed Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title_short Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
title_sort efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal–organic framework as efficient and reusable catalyst
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9209509/
https://www.ncbi.nlm.nih.gov/pubmed/35725895
http://dx.doi.org/10.1038/s41598-022-14341-4
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