A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil

Malania oleifera Chum is a unique renewable plant resource in China, its fruit oil has a high content of 15-tetracosenic acid, and it is a good raw material for the synthesis of cyclopentadecanone and cyclopentadecanolide. A Novel synthesis method of cyclopentadecanone and cyclopentadecanolide from...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Pin, Li, Weiguang, Liu, Xiongmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2022
Materias:
Research
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9219129/
https://www.ncbi.nlm.nih.gov/pubmed/35733143
http://dx.doi.org/10.1186/s13065-022-00840-y
_version_ 1784732041760210944
author Liu, Pin
Li, Weiguang
Liu, Xiongmin
author_facet Liu, Pin
Li, Weiguang
Liu, Xiongmin
author_sort Liu, Pin
collection PubMed
description Malania oleifera Chum is a unique renewable plant resource in China, its fruit oil has a high content of 15-tetracosenic acid, and it is a good raw material for the synthesis of cyclopentadecanone and cyclopentadecanolide. A Novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil was designed, and the synthesis yields of c cyclopentadecanone and cyclopentadecanolide were 38.5% and 63.0%, respectively. The effect of different ester groups on cyclization of α,ω-difatty acid alkyl ester in cyclopentadecanone synthesis, and effect of catalysts on cyclization ofω-hydroxycarboxylic acid triglyceride in cyclopentadecanolide synthesis were investigated. The designed synthesis strategy has the characteristics of less synthesis steps and high utilization efficiency of 15-tetracosenic acid, which has simple and economic. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s13065-022-00840-y.
format Online
Article
Text
id pubmed-9219129
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher Springer International Publishing
record_format MEDLINE/PubMed
spelling pubmed-92191292022-06-24 A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil Liu, Pin Li, Weiguang Liu, Xiongmin BMC Chem Research Malania oleifera Chum is a unique renewable plant resource in China, its fruit oil has a high content of 15-tetracosenic acid, and it is a good raw material for the synthesis of cyclopentadecanone and cyclopentadecanolide. A Novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil was designed, and the synthesis yields of c cyclopentadecanone and cyclopentadecanolide were 38.5% and 63.0%, respectively. The effect of different ester groups on cyclization of α,ω-difatty acid alkyl ester in cyclopentadecanone synthesis, and effect of catalysts on cyclization ofω-hydroxycarboxylic acid triglyceride in cyclopentadecanolide synthesis were investigated. The designed synthesis strategy has the characteristics of less synthesis steps and high utilization efficiency of 15-tetracosenic acid, which has simple and economic. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s13065-022-00840-y. Springer International Publishing 2022-06-22 /pmc/articles/PMC9219129/ /pubmed/35733143 http://dx.doi.org/10.1186/s13065-022-00840-y Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/ (https://creativecommons.org/publicdomain/zero/1.0/) ) applies to the data made available in this article, unless otherwise stated in a credit line to the data.
spellingShingle Research
Liu, Pin
Li, Weiguang
Liu, Xiongmin
A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title_full A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title_fullStr A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title_full_unstemmed A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title_short A novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
title_sort novel synthesis method of cyclopentadecanone and cyclopentadecanolide from vegetable oil
topic Research
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9219129/
https://www.ncbi.nlm.nih.gov/pubmed/35733143
http://dx.doi.org/10.1186/s13065-022-00840-y
work_keys_str_mv AT liupin anovelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil
AT liweiguang anovelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil
AT liuxiongmin anovelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil
AT liupin novelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil
AT liweiguang novelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil
AT liuxiongmin novelsynthesismethodofcyclopentadecanoneandcyclopentadecanolidefromvegetableoil

Ejemplares similares