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Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment
This paper discusses the processes of the long-lived (137)Cs and (60)Co immobilization on titanium surfaces in simulated light water reactor primary circuit environments. This study is prompted by numerous problems in both the maintenance of equipment during reactor operation and the dismantling of...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227557/ https://www.ncbi.nlm.nih.gov/pubmed/35744319 http://dx.doi.org/10.3390/ma15124261 |
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author | Glukhoedov, Nikita A. Epimakhov, Vitaliy N. Orlov, Sergey N. Tsapko, Anastasiya A. Zmitrodan, Aleksandr A. Zmitrodan, Grigoriy A. Skripkin, Mikhail Yu. |
author_facet | Glukhoedov, Nikita A. Epimakhov, Vitaliy N. Orlov, Sergey N. Tsapko, Anastasiya A. Zmitrodan, Aleksandr A. Zmitrodan, Grigoriy A. Skripkin, Mikhail Yu. |
author_sort | Glukhoedov, Nikita A. |
collection | PubMed |
description | This paper discusses the processes of the long-lived (137)Cs and (60)Co immobilization on titanium surfaces in simulated light water reactor primary circuit environments. This study is prompted by numerous problems in both the maintenance of equipment during reactor operation and the dismantling of the reactor after the completion of the operation, which is associated with contamination of working surfaces with long-lived radionuclides. The composition of the oxide films formed on the surface of commercial titanium alloy ПT-3B has been studied with specimens prepared in autoclave test conditions and surface samples from the pipeline sections to which the primary coolant was applied. These films on the coolant pipeline surface consist of a titanium dioxide layer tightly adhered to the pipeline metal surface and weakly fixed deposits—crystallites comprised of titanium oxides and other corrosion products (oxides and hydrated oxides of iron, nickel, chromium etc.). The radionuclide composition of the samples was studied by gamma-spectrometry. It is shown that the mechanism of titanium-surface contamination with (137)Cs is by physisorption, contamination level increases upon the presence of dispersed particles. For (60)Co, both sorption and deposition onto surfaces are observed. |
format | Online Article Text |
id | pubmed-9227557 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-92275572022-06-25 Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment Glukhoedov, Nikita A. Epimakhov, Vitaliy N. Orlov, Sergey N. Tsapko, Anastasiya A. Zmitrodan, Aleksandr A. Zmitrodan, Grigoriy A. Skripkin, Mikhail Yu. Materials (Basel) Article This paper discusses the processes of the long-lived (137)Cs and (60)Co immobilization on titanium surfaces in simulated light water reactor primary circuit environments. This study is prompted by numerous problems in both the maintenance of equipment during reactor operation and the dismantling of the reactor after the completion of the operation, which is associated with contamination of working surfaces with long-lived radionuclides. The composition of the oxide films formed on the surface of commercial titanium alloy ПT-3B has been studied with specimens prepared in autoclave test conditions and surface samples from the pipeline sections to which the primary coolant was applied. These films on the coolant pipeline surface consist of a titanium dioxide layer tightly adhered to the pipeline metal surface and weakly fixed deposits—crystallites comprised of titanium oxides and other corrosion products (oxides and hydrated oxides of iron, nickel, chromium etc.). The radionuclide composition of the samples was studied by gamma-spectrometry. It is shown that the mechanism of titanium-surface contamination with (137)Cs is by physisorption, contamination level increases upon the presence of dispersed particles. For (60)Co, both sorption and deposition onto surfaces are observed. MDPI 2022-06-16 /pmc/articles/PMC9227557/ /pubmed/35744319 http://dx.doi.org/10.3390/ma15124261 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Glukhoedov, Nikita A. Epimakhov, Vitaliy N. Orlov, Sergey N. Tsapko, Anastasiya A. Zmitrodan, Aleksandr A. Zmitrodan, Grigoriy A. Skripkin, Mikhail Yu. Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title | Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title_full | Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title_fullStr | Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title_full_unstemmed | Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title_short | Sorption of (137)Cs and (60)Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment |
title_sort | sorption of (137)cs and (60)co on titanium oxide films in light water reactor primary circuit environment |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227557/ https://www.ncbi.nlm.nih.gov/pubmed/35744319 http://dx.doi.org/10.3390/ma15124261 |
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