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Competing Metal–Ligand Interactions in Tris(cyclopentadienyl)-cyclohexylisonitrile Complexes of Trivalent Actinides and Lanthanides

The structure and bonding properties of 16 complexes formed by trivalent f elements (M=U, Np, Pu and lanthanides except for Pm and Pr) with cyclopentadienyl (Cp) and cyclohexylisonitrile (C≡NCy) ligands, (Cp)(3)M(C≡NCy), were studied by a joint experimental (XRD, NMR) and theoretical (DFT) analysis....

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Detalles Bibliográficos
Autores principales: Kovács, Attila, Apostolidis, Christos, Walter, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9228681/
https://www.ncbi.nlm.nih.gov/pubmed/35744936
http://dx.doi.org/10.3390/molecules27123811