Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas

A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical str...

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Detalles Bibliográficos
Autores principales: Pan, Jie, Li, Haocong, Sun, Kai, Tang, Shi, Yu, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229220/
https://www.ncbi.nlm.nih.gov/pubmed/35744775
http://dx.doi.org/10.3390/molecules27123648
Descripción
Sumario:A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system’s ppm Fe.

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