Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas

A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical str...

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Detalles Bibliográficos
Autores principales: Pan, Jie, Li, Haocong, Sun, Kai, Tang, Shi, Yu, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229220/
https://www.ncbi.nlm.nih.gov/pubmed/35744775
http://dx.doi.org/10.3390/molecules27123648
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author Pan, Jie
Li, Haocong
Sun, Kai
Tang, Shi
Yu, Bing
author_facet Pan, Jie
Li, Haocong
Sun, Kai
Tang, Shi
Yu, Bing
author_sort Pan, Jie
collection PubMed
description A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system’s ppm Fe.
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spelling pubmed-92292202022-06-25 Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas Pan, Jie Li, Haocong Sun, Kai Tang, Shi Yu, Bing Molecules Article A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system’s ppm Fe. MDPI 2022-06-07 /pmc/articles/PMC9229220/ /pubmed/35744775 http://dx.doi.org/10.3390/molecules27123648 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pan, Jie
Li, Haocong
Sun, Kai
Tang, Shi
Yu, Bing
Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title_full Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title_fullStr Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title_full_unstemmed Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title_short Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
title_sort visible-light-induced decarboxylation of dioxazolones to phosphinimidic amides and ureas
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229220/
https://www.ncbi.nlm.nih.gov/pubmed/35744775
http://dx.doi.org/10.3390/molecules27123648
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AT sunkai visiblelightinduceddecarboxylationofdioxazolonestophosphinimidicamidesandureas
AT tangshi visiblelightinduceddecarboxylationofdioxazolonestophosphinimidicamidesandureas
AT yubing visiblelightinduceddecarboxylationofdioxazolonestophosphinimidicamidesandureas

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