Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors

Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, Cat(2){[SnBr(6)](I(2))} (Cat = Me(4)N(+) (1), 1-MePy(+) (2) and 4-MePyH (3)), were synthesized. In all cases, I(2) linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were...

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Detalles Bibliográficos
Autores principales: Korobeynikov, Nikita A., Usoltsev, Andrey N., Abramov, Pavel A., Sokolov, Maxim N., Adonin, Sergey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229721/
https://www.ncbi.nlm.nih.gov/pubmed/35744981
http://dx.doi.org/10.3390/molecules27123859
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author Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
author_facet Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
author_sort Korobeynikov, Nikita A.
collection PubMed
description Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, Cat(2){[SnBr(6)](I(2))} (Cat = Me(4)N(+) (1), 1-MePy(+) (2) and 4-MePyH (3)), were synthesized. In all cases, I(2) linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that 1–3 are narrow band gap semiconductors.
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spelling pubmed-92297212022-06-25 Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors Korobeynikov, Nikita A. Usoltsev, Andrey N. Abramov, Pavel A. Sokolov, Maxim N. Adonin, Sergey A. Molecules Communication Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, Cat(2){[SnBr(6)](I(2))} (Cat = Me(4)N(+) (1), 1-MePy(+) (2) and 4-MePyH (3)), were synthesized. In all cases, I(2) linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that 1–3 are narrow band gap semiconductors. MDPI 2022-06-16 /pmc/articles/PMC9229721/ /pubmed/35744981 http://dx.doi.org/10.3390/molecules27123859 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title_full Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title_fullStr Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title_full_unstemmed Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title_short Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
title_sort supramolecular diiodine-bromostannate(iv) complexes: narrow bandgap semiconductors
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229721/
https://www.ncbi.nlm.nih.gov/pubmed/35744981
http://dx.doi.org/10.3390/molecules27123859
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