Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres

A series of novel crosslinked polyphosphazene-aromatic ether organic–inorganic hybrid microspheres with different structures were prepared via precipitation polycondensation between hexachlorocyclotriphosphazene (HCCP) and bisphenol monomers. The bisphenol monomers have different numbers of –CF(3) i...

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Detalles Bibliográficos
Autores principales: Wang, Yan, Yu, Yunwu, Li, Long, Zhang, Hongbo, Chen, Zheng, Yang, Yanchao, Jiang, Zhenhua, Mu, Jianxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229955/
https://www.ncbi.nlm.nih.gov/pubmed/35745985
http://dx.doi.org/10.3390/polym14122411
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author Wang, Yan
Yu, Yunwu
Li, Long
Zhang, Hongbo
Chen, Zheng
Yang, Yanchao
Jiang, Zhenhua
Mu, Jianxin
author_facet Wang, Yan
Yu, Yunwu
Li, Long
Zhang, Hongbo
Chen, Zheng
Yang, Yanchao
Jiang, Zhenhua
Mu, Jianxin
author_sort Wang, Yan
collection PubMed
description A series of novel crosslinked polyphosphazene-aromatic ether organic–inorganic hybrid microspheres with different structures were prepared via precipitation polycondensation between hexachlorocyclotriphosphazene (HCCP) and bisphenol monomers. The bisphenol monomers have different numbers of –CF(3) in the side group, which correspond to distinct oligomeric species-absorbing mechanisms. The wetting behavior of the microsphere surface was evaluated using a water contact angle (CA) measurement, which increased with the increase in the content of –CF(3) in polyphosphazene. We also investigated the effects of HCCP concentration and ultrasonic power on the morphology of the microspheres.
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spelling pubmed-92299552022-06-25 Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres Wang, Yan Yu, Yunwu Li, Long Zhang, Hongbo Chen, Zheng Yang, Yanchao Jiang, Zhenhua Mu, Jianxin Polymers (Basel) Article A series of novel crosslinked polyphosphazene-aromatic ether organic–inorganic hybrid microspheres with different structures were prepared via precipitation polycondensation between hexachlorocyclotriphosphazene (HCCP) and bisphenol monomers. The bisphenol monomers have different numbers of –CF(3) in the side group, which correspond to distinct oligomeric species-absorbing mechanisms. The wetting behavior of the microsphere surface was evaluated using a water contact angle (CA) measurement, which increased with the increase in the content of –CF(3) in polyphosphazene. We also investigated the effects of HCCP concentration and ultrasonic power on the morphology of the microspheres. MDPI 2022-06-14 /pmc/articles/PMC9229955/ /pubmed/35745985 http://dx.doi.org/10.3390/polym14122411 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Yan
Yu, Yunwu
Li, Long
Zhang, Hongbo
Chen, Zheng
Yang, Yanchao
Jiang, Zhenhua
Mu, Jianxin
Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title_full Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title_fullStr Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title_full_unstemmed Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title_short Preparation and Properties of Novel Crosslinked Polyphosphazene-Aromatic Ethers Organic–Inorganic Hybrid Microspheres
title_sort preparation and properties of novel crosslinked polyphosphazene-aromatic ethers organic–inorganic hybrid microspheres
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229955/
https://www.ncbi.nlm.nih.gov/pubmed/35745985
http://dx.doi.org/10.3390/polym14122411
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