Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer

A pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag(20). The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral nanocluster complexes e...

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Detalles Bibliográficos
Autores principales: Guo, Yan, Han, Ying, Chen, Chuanfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9230552/
https://www.ncbi.nlm.nih.gov/pubmed/35745054
http://dx.doi.org/10.3390/molecules27123932
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author Guo, Yan
Han, Ying
Chen, Chuanfeng
author_facet Guo, Yan
Han, Ying
Chen, Chuanfeng
author_sort Guo, Yan
collection PubMed
description A pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag(20). The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral nanocluster complexes exhibited enhanced luminescence and induced CD signals at room temperature in the solid state, revealing the stable complexation and chirality transfer from the chiral macrocycles to the nanocluster Ag(20).
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spelling pubmed-92305522022-06-25 Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer Guo, Yan Han, Ying Chen, Chuanfeng Molecules Article A pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag(20). The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral nanocluster complexes exhibited enhanced luminescence and induced CD signals at room temperature in the solid state, revealing the stable complexation and chirality transfer from the chiral macrocycles to the nanocluster Ag(20). MDPI 2022-06-19 /pmc/articles/PMC9230552/ /pubmed/35745054 http://dx.doi.org/10.3390/molecules27123932 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Guo, Yan
Han, Ying
Chen, Chuanfeng
Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title_full Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title_fullStr Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title_full_unstemmed Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title_short Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag(20): Emission Enhancement and Chirality Transfer
title_sort chiral nanocluster complexes formed by host−guest interaction between enantiomeric 2,6-helic[6]arenes and silver cluster ag(20): emission enhancement and chirality transfer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9230552/
https://www.ncbi.nlm.nih.gov/pubmed/35745054
http://dx.doi.org/10.3390/molecules27123932
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AT chenchuanfeng chiralnanoclustercomplexesformedbyhostguestinteractionbetweenenantiomeric26helic6arenesandsilverclusterag20emissionenhancementandchiralitytransfer

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