Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes

The synthesis of sulfur-bridged Fe–Ni heterobimetallics was inspired by Nature’s strategies to “trick” abundant first row transition metals into enabling 2-electron processes: redox-active ligands (including pendant iron–sulfur clusters) and proximal metals. Our design to have redox-active ligands o...

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Detalles Bibliográficos
Autores principales: Quiroz, Manuel, Lockart, Molly M., Saber, Mohamed R., Vali, Shaik Waseem, Elrod, Lindy C., Pierce, Brad S., Hall, Michael B., Darensbourg, Marcetta Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2022
Materias:
Physical Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9233302/
https://www.ncbi.nlm.nih.gov/pubmed/35696567
http://dx.doi.org/10.1073/pnas.2201240119

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