Improving the Stability and Efficiency of Perovskite Solar Cells by a Bidentate Anilinium Salt

[Image: see text] We report improvement in the perovskite solar cell efficiency and stability after passivation with an organic molecule decorated with two anilinium cations. We compare this salt with its neutral analog and found that the change in the electron density distribution upon protonation...

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Detalles Bibliográficos
Autores principales: Scalon, Lucas, Szostak, Rodrigo, Araújo, Francineide L., Adriani, Karla F., Silveira, Julian F. R. V., Oliveira, Willian X. C., Da Silva, Juarez L. F., Oliveira, Caio C., Nogueira, Ana Flávia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241004/
https://www.ncbi.nlm.nih.gov/pubmed/35783170
http://dx.doi.org/10.1021/jacsau.2c00151
Descripción
Sumario:[Image: see text] We report improvement in the perovskite solar cell efficiency and stability after passivation with an organic molecule decorated with two anilinium cations. We compare this salt with its neutral analog and found that the change in the electron density distribution upon protonation and the presence of the halide anion are key to explaining the better passivation ability of the salt. In addition, we show that the counteranion has a significant impact on the performance of the device.

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