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Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials
Fabricating a simple and valid high-property graphene-based supercapacitor employing engineered plastic waste as the original material has attracted tremendous interest. Herein we report an extendable method for producing nitrogen and phosphorus dual-doped porous three-dimensional (3D) graphene mate...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241056/ https://www.ncbi.nlm.nih.gov/pubmed/35865584 http://dx.doi.org/10.1039/d2ra02477b |
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author | Yang, Weiwei Yu, Chao Meng, Fanxing |
author_facet | Yang, Weiwei Yu, Chao Meng, Fanxing |
author_sort | Yang, Weiwei |
collection | PubMed |
description | Fabricating a simple and valid high-property graphene-based supercapacitor employing engineered plastic waste as the original material has attracted tremendous interest. Herein we report an extendable method for producing nitrogen and phosphorus dual-doped porous three-dimensional (3D) graphene materials from the blends of ammonium polyphosphate (APP) and polycarbonate (PC)/acrylonitrile ((A), butadiene (B), and styrene (S)) (ABS) using a simple laser direct-writing technique. In APP/PC/ABS blends, APP/PC/ABS, a waste by-product generated in car interiors and exterior decoration and electronic device shells and other fields, served as a sufficient and economic carbon source, while APP was employed as a nitrogen and phosphorus source as well as flame retardant. APP/PC/ABS blends could be transformed into nitrogen and phosphorus dual-doped laser-induced graphene (NPLIG) via scribing under a CO(2) laser in air conditions. In addition, a supercapacitor was fabricated applying NPLIG as the electrode material, and KOH solution as the electrolyte. The as-fabricated NPLIG supercapacitor exhibited excellent electrochemical behaviours, namely, a high specific areal capacitance (239 F g(−1)) at a current density of 0.05 A g(−1), which outperformed many LIG-based and GO-based supercapacitors. The concept of designing supercapacitors that can be obtained with a facile laser-scribing technology can stimulate both the building of supercapacitors and preparation of graphene, and the sustainable utilization of engineering plastics. |
format | Online Article Text |
id | pubmed-9241056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-92410562022-07-20 Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials Yang, Weiwei Yu, Chao Meng, Fanxing RSC Adv Chemistry Fabricating a simple and valid high-property graphene-based supercapacitor employing engineered plastic waste as the original material has attracted tremendous interest. Herein we report an extendable method for producing nitrogen and phosphorus dual-doped porous three-dimensional (3D) graphene materials from the blends of ammonium polyphosphate (APP) and polycarbonate (PC)/acrylonitrile ((A), butadiene (B), and styrene (S)) (ABS) using a simple laser direct-writing technique. In APP/PC/ABS blends, APP/PC/ABS, a waste by-product generated in car interiors and exterior decoration and electronic device shells and other fields, served as a sufficient and economic carbon source, while APP was employed as a nitrogen and phosphorus source as well as flame retardant. APP/PC/ABS blends could be transformed into nitrogen and phosphorus dual-doped laser-induced graphene (NPLIG) via scribing under a CO(2) laser in air conditions. In addition, a supercapacitor was fabricated applying NPLIG as the electrode material, and KOH solution as the electrolyte. The as-fabricated NPLIG supercapacitor exhibited excellent electrochemical behaviours, namely, a high specific areal capacitance (239 F g(−1)) at a current density of 0.05 A g(−1), which outperformed many LIG-based and GO-based supercapacitors. The concept of designing supercapacitors that can be obtained with a facile laser-scribing technology can stimulate both the building of supercapacitors and preparation of graphene, and the sustainable utilization of engineering plastics. The Royal Society of Chemistry 2022-06-29 /pmc/articles/PMC9241056/ /pubmed/35865584 http://dx.doi.org/10.1039/d2ra02477b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Yang, Weiwei Yu, Chao Meng, Fanxing Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title | Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title_full | Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title_fullStr | Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title_full_unstemmed | Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title_short | Recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
title_sort | recycling and applications of ammonium polyphosphate/polycarbonate/acrylonitrile butadiene styrene by laser-scribing technologies for supercapacitor electrode materials |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241056/ https://www.ncbi.nlm.nih.gov/pubmed/35865584 http://dx.doi.org/10.1039/d2ra02477b |
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