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Calcium Bistriflimide-Mediated Sulfur(VI)–Fluoride Exchange (SuFEx): Mechanistic Insights toward Instigating Catalysis

[Image: see text] We report a mechanistic investigation of calcium bistriflimide-mediated sulfur(VI)–fluoride exchange (SuFEx) between sulfonyl fluorides and amines. We determine the likely pre-activation resting state—a calcium bistriflimide complex with ligated amines—thus allowing for corroborate...

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Detalles Bibliográficos
Autores principales:	Han, Brian, Khasnavis, Samuel R., Nwerem, Matthew, Bertagna, Michael, Ball, Nicholas D., Ogba, O. Maduka
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241145/ https://www.ncbi.nlm.nih.gov/pubmed/35700314 http://dx.doi.org/10.1021/acs.inorgchem.2c01230

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