Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes

A new diplumbane, namely [Pb(CH(2)SiMe(3))(3)](2), was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents, leading to the synthesis of a range of a...

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Autores principales: Zhang, Guoqi, Li, Sihan, Zeng, Haisu, Zheng, Shengping, Neary, Michelle C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241624/
https://www.ncbi.nlm.nih.gov/pubmed/35865571
http://dx.doi.org/10.1039/d2ra03731a
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author Zhang, Guoqi
Li, Sihan
Zeng, Haisu
Zheng, Shengping
Neary, Michelle C.
author_facet Zhang, Guoqi
Li, Sihan
Zeng, Haisu
Zheng, Shengping
Neary, Michelle C.
author_sort Zhang, Guoqi
collection PubMed
description A new diplumbane, namely [Pb(CH(2)SiMe(3))(3)](2), was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents, leading to the synthesis of a range of alcohols in high yields after hydrolysis.
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spelling pubmed-92416242022-07-20 Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes Zhang, Guoqi Li, Sihan Zeng, Haisu Zheng, Shengping Neary, Michelle C. RSC Adv Chemistry A new diplumbane, namely [Pb(CH(2)SiMe(3))(3)](2), was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents, leading to the synthesis of a range of alcohols in high yields after hydrolysis. The Royal Society of Chemistry 2022-06-29 /pmc/articles/PMC9241624/ /pubmed/35865571 http://dx.doi.org/10.1039/d2ra03731a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Zhang, Guoqi
Li, Sihan
Zeng, Haisu
Zheng, Shengping
Neary, Michelle C.
Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title_full Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title_fullStr Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title_full_unstemmed Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title_short Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
title_sort diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241624/
https://www.ncbi.nlm.nih.gov/pubmed/35865571
http://dx.doi.org/10.1039/d2ra03731a
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AT zhengshengping diplumbanecatalysedsolventandadditivefreehydroborationofketonesandaldehydes
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