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Cu-catalyzed carboboration of acetylene with Michael acceptors

A copper-catalyzed three-component carboboration of acetylene with B(2)Pin(2) and Michael acceptors is reported. In this reaction, a cheap and abundant C2 chemical feedstock, acetylene, was used as a starting material to afford cis-alkenyl boronates bearing a homoallylic carbonyl group. The reaction...

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Detalles Bibliográficos
Autores principales: Cheng, Tairan, Liu, Boxiang, Wu, Rui, Zhu, Shifa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241969/
https://www.ncbi.nlm.nih.gov/pubmed/35872813
http://dx.doi.org/10.1039/d2sc02306g