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CO reductive oligomerization by a divalent thulium complex and CO(2)-induced functionalization

The divalent thulium complex [Tm(Cp(ttt))(2)] (Cp(ttt) = 1,2,4-tris(tert-butyl)cyclopentadienyl) reacts with CO to afford selective CO reductive dimerization and trimerization into ethynediolate (C(2)) and ketenecarboxylate (C(3)) complexes, respectively. DFT calculations were performed to shed ligh...

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Detalles Bibliográficos
Autores principales:	Simler, Thomas, McCabe, Karl N., Maron, Laurent, Nocton, Grégory
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9241974/ https://www.ncbi.nlm.nih.gov/pubmed/35919756 http://dx.doi.org/10.1039/d2sc01798a

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