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Dynamical law of the phase interface motion in the presence of crystals nucleation
In this paper, we develop a theory of solid/liquid phase interface motion into an undercooled melt in the presence of nucleation and growth of crystals. A set of integrodifferential kinetic, heat and mass transfer equations is analytically solved in the two-phase and liquid layers divided by the mov...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9243072/ https://www.ncbi.nlm.nih.gov/pubmed/35768561 http://dx.doi.org/10.1038/s41598-022-15137-2 |
Sumario: | In this paper, we develop a theory of solid/liquid phase interface motion into an undercooled melt in the presence of nucleation and growth of crystals. A set of integrodifferential kinetic, heat and mass transfer equations is analytically solved in the two-phase and liquid layers divided by the moving phase transition interface. To do this, we have used the saddle-point method to evaluate a Laplace-type integral and the small parameter method to find the law of phase interface motion. The main result is that the phase interface Z propagates into an undercooled melt with time t as [Formula: see text] with allowance for crystal nucleation. The effect of nucleation is in the second contribution, which is proportional to [Formula: see text] whereas the first term [Formula: see text] represents the well-known self-similar solution. The nucleation and crystal growth processes are responsible for the emission of latent crystallization heat, which reduces the melt undercooling and constricts the two-phase layer thickness (parameter [Formula: see text] ). |
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