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Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process

[Image: see text] In this study, a superhydrophobic coating on glass has been prepared through a single-step aerosol-assisted chemical vapor deposition (AACVD) process. During the process, an aerosolized precursor containing polydimethylsiloxane, epoxy resin, and stearic acid functionalized Al-doped...

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Autores principales: Park, Seonghyeok, Huo, Jiatong, Shin, Juhun, Heo, Ki Joon, Kalmoni, Julie Jalila, Sathasivam, Sanjayan, Hwang, Gi Byoung, Carmalt, Claire J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9245182/
https://www.ncbi.nlm.nih.gov/pubmed/35696726
http://dx.doi.org/10.1021/acs.langmuir.2c01060
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author Park, Seonghyeok
Huo, Jiatong
Shin, Juhun
Heo, Ki Joon
Kalmoni, Julie Jalila
Sathasivam, Sanjayan
Hwang, Gi Byoung
Carmalt, Claire J.
author_facet Park, Seonghyeok
Huo, Jiatong
Shin, Juhun
Heo, Ki Joon
Kalmoni, Julie Jalila
Sathasivam, Sanjayan
Hwang, Gi Byoung
Carmalt, Claire J.
author_sort Park, Seonghyeok
collection PubMed
description [Image: see text] In this study, a superhydrophobic coating on glass has been prepared through a single-step aerosol-assisted chemical vapor deposition (AACVD) process. During the process, an aerosolized precursor containing polydimethylsiloxane, epoxy resin, and stearic acid functionalized Al-doped ZnO nanoparticles was deposited onto the glass at 350 °C. X-ray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy showed that the precursor was successfully coated and formed a nano/microstructure (surface roughness: 378.0 ± 46.1 nm) on the glass surface. The coated surface had a water contact angle of 159.1 ± 1.2°, contact angle hysteresis of 2.2 ± 1.7°, and rolling off-angle of 1°, indicating that it was superhydrophobic. In the self-cleaning test of the coated surface at a tilted angle of 20°, it was shown that water droplets rolled and washed out dirt on the surface. The stability tests showed that the surface remained superhydrophobic after 120 h of exposure to ultraviolet (UV) irradiation and even after heat exposure at 350 °C. In addition, the surface was highly repellent to water solutions of pH 1–13. The results showed that the addition of the functionalized nanoparticles into the precursor allowed for the control of surface roughness and provided a simplified single-step fabrication process of the superhydrophobic surface. This provides valuable information for developing the manufacturing process for superhydrophobic surfaces.
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spelling pubmed-92451822022-07-01 Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process Park, Seonghyeok Huo, Jiatong Shin, Juhun Heo, Ki Joon Kalmoni, Julie Jalila Sathasivam, Sanjayan Hwang, Gi Byoung Carmalt, Claire J. Langmuir [Image: see text] In this study, a superhydrophobic coating on glass has been prepared through a single-step aerosol-assisted chemical vapor deposition (AACVD) process. During the process, an aerosolized precursor containing polydimethylsiloxane, epoxy resin, and stearic acid functionalized Al-doped ZnO nanoparticles was deposited onto the glass at 350 °C. X-ray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy showed that the precursor was successfully coated and formed a nano/microstructure (surface roughness: 378.0 ± 46.1 nm) on the glass surface. The coated surface had a water contact angle of 159.1 ± 1.2°, contact angle hysteresis of 2.2 ± 1.7°, and rolling off-angle of 1°, indicating that it was superhydrophobic. In the self-cleaning test of the coated surface at a tilted angle of 20°, it was shown that water droplets rolled and washed out dirt on the surface. The stability tests showed that the surface remained superhydrophobic after 120 h of exposure to ultraviolet (UV) irradiation and even after heat exposure at 350 °C. In addition, the surface was highly repellent to water solutions of pH 1–13. The results showed that the addition of the functionalized nanoparticles into the precursor allowed for the control of surface roughness and provided a simplified single-step fabrication process of the superhydrophobic surface. This provides valuable information for developing the manufacturing process for superhydrophobic surfaces. American Chemical Society 2022-06-13 2022-06-28 /pmc/articles/PMC9245182/ /pubmed/35696726 http://dx.doi.org/10.1021/acs.langmuir.2c01060 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Park, Seonghyeok
Huo, Jiatong
Shin, Juhun
Heo, Ki Joon
Kalmoni, Julie Jalila
Sathasivam, Sanjayan
Hwang, Gi Byoung
Carmalt, Claire J.
Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title_full Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title_fullStr Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title_full_unstemmed Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title_short Production of an EP/PDMS/SA/AlZnO Coated Superhydrophobic Surface through an Aerosol-Assisted Chemical Vapor Deposition Process
title_sort production of an ep/pdms/sa/alzno coated superhydrophobic surface through an aerosol-assisted chemical vapor deposition process
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9245182/
https://www.ncbi.nlm.nih.gov/pubmed/35696726
http://dx.doi.org/10.1021/acs.langmuir.2c01060
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