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Abrupt change from moderate positive to colossal negative thermal expansion caused by imidazolate composite formation
This work describes temperature-induced crystallization processes and reaction mechanisms occurring in the borohydride-imidazolate system. In the course of thermal evolution, crystal structures of two novel bimetallic imidazolates AMnIm(3) (A = Na, K) were solved using synchrotron radiation powder d...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer US
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9246808/ https://www.ncbi.nlm.nih.gov/pubmed/35789923 http://dx.doi.org/10.1007/s10853-022-07360-z |